[A14433] CAS 626-35-7 | Ethyl nitroacetate, 97% | Alfa
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Brand: Alfa Aesar
626-35-7 | C4H7NO4 | nitroacetic acid ethyl ester
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Chemical Identifiers
CAS
626-35-7
Molecular Weight (g/mol)
133.10
Synonym
nitroacetic acid ethyl ester
SMILES
CCOC(=O)C[N+]([O-])=O
InChI Key
FTKASJMIPSSXBP-UHFFFAOYSA-N
Molecular Formula
C4H7NO4
IUPAC Name
ethyl 2-nitroacetate
Specifications
Appearance (Color)
Clear colorless to pale yellow
Identification (FTIR)
Conforms
Assay (GC)
≥96.0%
Refractive Index
1.4220-1.4270 @ 20?C
Form
Liquid
설명
Ethyl nitroacetate has been used in the synthesis of γ-oxoacids via Michael addition reaction with α,β-unsaturated ketones, fuctionalization of C4-position on pyrimidine and C6-position on 2-deoxyguanosine to produce novel nucleosides, facile synthesis of α,α-diisobutylglycine, synthesis of DL-4,4-difluoroglutamic acid. It is also used as an intermediate in the preparation of unsubstituted amino acids.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Ethyl nitroacetate has been used in the synthesis of γ-oxoacids via Michael addition reaction with α,β-unsaturated ketones, fuctionalization of C4-position on pyrimidine and C6-position on 2′-deoxyguanosine to produce novel nucleosides, facile synthesis of α,α-diisobutylglycine, synthesis of DL-4,4-difluoroglutamic acid. It is also used as an intermediate in the preparation of unsubstituted amino acids.
Ethyl nitroacetate has been used in the synthesis of γ-oxoacids via Michael addition reaction with α,β-unsaturated ketones, fuctionalization of C4-position on pyrimidine and C6-position on 2′-deoxyguanosine to produce novel nucleosides, facile synthesis of α,α-diisobutylglycine, synthesis of DL-4,4-difluoroglutamic acid. It is also used as an intermediate in the preparation of unsubstituted amino acids.
Solubility
Slightly soluble in water. Soluble in chloroform and ethyl acetate.
Notes
Store away from bases and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Other References:
Beilstein:1210027
GHS Hazard and Precautionary Statements
Hazard Statements:H227-H315-H319
GHS H StatementH315-H319-H227Causes skin irritation.Causes serious eye irritation.Combustible liquid.
Precautionary Statements:P210-P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362-P370+P378q-P501c
Risk & Safety
TSCA:YesRTECS Number:AJ1074000
경고:RUO – Research Use Only
CAS626-35-7FORMULAC4H7NO4EINECS210-944-7MDLMFCD00007403
| Pakage | 100g, 1g, 25g, 5g |
|---|---|
| brand | Alfa Aesar |
