[A17373] CAS 614-45-9 | tert-Butyl peroxybenzoate, 98%

CAS : 614-45-9
UN# : UN3103
MDL : MFCD00008802
Hazard Class : 5.2
EINECS : 210-382-2
Packing Group : II

Other name :

tert-Butyl perbenzoate

Chemical Properties

Formula : C11H14O3
Formula weight : 194.23
Melting Point : 6-8°
Boiling Point : 75-76°/0.2mm
Flash point : 93°(199°F)
Density : 1.042
Refractive Index : 1.4990
Sensitivity : Keep Cold.
Form : Liquid
Solubility : Soluble in ether, alcohol, ester, and ketones. Insoluble in water.

Literature References

For free-radical allylic benzoyloxylation of cyclohexene, promoted by CuBr, and references for preparation of benzoyloxy derivatives of other classes of compound including hydrocarbons, esters, ethers, sulfides, amides, etc., see: Org. Synth. Coll., 5, 70 (1973). The reaction with alkenes is also efficiently promoted by a complex of Cu(OTf)2 with DBN or DBU: Tetrahedron Lett., 37, 8435 (1996). For a review of acyloxylation at carbon, see: Synthesis, 1 (1972). In the presence of CuBr, effects dehydrogenation of oxazolines and thioazolines to the aromatized systems: J. Org. Chem., 61, 8207 (1996). Promotes Pd-catalyzed oxidative coupling of electron-rich aromatics with electron-deficient alkenes: Tetrahedron, 40, 2699 (1984). Promotes the free-radical addition of bisulfite to vinyltrimethylsilane, in an improved preparation of 2-(TMS)ethanesulfonyl chloride: Org. Synth., 75, 161 (1997).

Notes

Other References:Beilstein: 1342734UN#: UN3103

Grade Specifications

Grade Specifications

Hazard Statements : H200-H242-H302-H315-H319-H227Unstable explosives.Heating may cause a fire.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.Combustible liquid.
Precautionary Statements : P210-P305+P351+P338-P373-P401a-P410-P501aKeep away from heat/sparks/open flames/hot surfaces. – No smoking.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.DO NOT fight fire when fire reaches explosives.Store in accordance with local/regional/national/international regulations.Protect from sunlight.Dispose of contents/container in accordance with local/regional/national/international regulations.