[A14662] CAS 762-72-1 | Allyltrimethylsilane, 98+% | Alfa
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Brand: Alfa Aesar
762-72-1 | C6H14Si | silane, trimethyl-2-propenyl-
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Chemical Identifiers
CAS
762-72-1
Molecular Weight (g/mol)
114.26
Synonym
silane, trimethyl-2-propenyl-
SMILES
C[Si](C)(C)CC=C
InChI Key
HYWCXWRMUZYRPH-UHFFFAOYSA-N
Molecular Formula
C6H14Si
IUPAC Name
trimethyl(prop-2-en-1-yl)silane
Specifications
Form
Liquid
Identification (FTIR)
Conforms
Appearance (Color)
Clear colorless
Assay (GC)
≥98.0%
Refractive Index
1.4060-1.4100 @ 20?C
설명
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
Solubility
Miscible with organic solvents. Immiscible with water.
Notes
Store in cool place. Incompatible with strong oxidizing agents and acids.
Other References:
UN Number:UN1993Beilstein:906755
GHS Hazard and Precautionary Statements
Hazard Statements:H225-H315-H319-H335
GHS H StatementH225-H315-H319-H335Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
Risk & Safety
TSCA:Yes
경고:RUO – Research Use Only
CAS762-72-1FORMULAC6H14SiHAZARD CLASS3EINECS212-104-5MDLMFCD00008635PACKAGING GROUPII
| Pakage | 10g, 250g, 50G |
|---|---|
| brand | Alfa Aesar |
