[L15152] CAS 15956-28-2 | Rhodium(II) acetate, dimer, 98+% | Alfa
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Brand: Alfa Aesar
15956-28-2 | C8H12O8Rh2 | tetramethyl-2,4,6,8,9,11,12,14-octaoxa-1,5-dirhodatetracyclo[3.3.3.3¹,⁵.0¹,⁵]tetradecane-1,1,5,5-tetrakis(ylium)-3,7,10,13-tetraide
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Chemical Identifiers
CAS
15956-28-2
Molecular Weight (g/mol)
441.99
MDL Number
MFCD00003538
Synonym
tetramethyl-2,4,6,8,9,11,12,14-octaoxa-1,5-dirhodatetracyclo[3.3.3.3¹,⁵.0¹,⁵]tetradecane-1,1,5,5-tetrakis(ylium)-3,7,10,13-tetraide
SMILES
C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4
InChI Key
VOXKIADTKKPBBP-UHFFFAOYSA-N
Molecular Formula
C8H12O8Rh2
IUPAC Name
tetramethyl-2,4,6,8,9,11,12,14-octaoxa-1,5-dirhodatetracyclo[3.3.3.3¹,⁵.0¹,⁵]tetradecane-1,1,5,5-tetrakis(ylium)-3,7,10,13-tetraide
Specifications
Appearance (Color)
Green
Assay (unspecified)
(by Elemental Rhodium): >98.0 to <102.0%
Form
Crystalline powder
Elemental Analysis
(Rhodium, Rh): 45.63-47.49%
설명
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ?-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ɑ-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ɑ-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.
Solubility
Soluble in aqueous solution like water. Slightly soluble in ethanol
Notes
Stable under normal conditions.
GHS Hazard and Precautionary Statements
Hazard Statements:H315-H319
Precautionary Statements:P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
Risk & Safety
TSCA:NoRTECS Number:VI9361000
경고:RUO – Research Use Only
CAS15956-28-2FORMULAC8H12O8Rh2EINECS240-084-8MDLMFCD00003538
| Pakage | 100mg, 2g, 500MG |
|---|---|
| brand | Alfa Aesar |
