[L15779] CAS 87413-09-0 | Dess-Martin periodinane | Alfa
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Brand: Alfa Aesar
87413-09-0 | C13H13IO8 | dess-martin periodinane
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Chemical Identifiers
CAS
87413-09-0
Molecular Weight (g/mol)
424.14
Synonym
dess-martin periodinane
SMILES
CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12
InChI Key
NKLCNNUWBJBICK-UHFFFAOYSA-N
Molecular Formula
C13H13IO8
IUPAC Name
1,1-bis(acetyloxy)-3-oxo-3H-1λ⁵,2-benziodaoxol-1-yl acetate
Specifications
Appearance (Color)
White
Form
Powder
Assay from Supplier’s CofA
≥97.0%
Proton NMR
Conforms to structure
설명
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.
Other References:
Merck Index:14,2933UN Number:UN1479Beilstein:4548207
GHS Hazard and Precautionary Statements
Hazard Statements:H272-H315-H319-H335
GHS H StatementH272-H315-H319-H335 May intensify fire; oxidizer.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P210-P220-P221-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS87413-09-0FORMULAC13H13IO8HAZARD CLASS5.1MDLMFCD00130127PACKAGING GROUPIII
| Pakage | 1g, 25g, 50G, 5g |
|---|---|
| brand | Alfa Aesar |
