[L20253] CAS 52093-28-4 | Samarium(III) trifluoromethanesulfonate, 98%

CAS : 52093-28-4
UN# : UN3261
MDL : MFCD00192431
Hazard Class : 8
EINECS : 000-000-0
Packing Group : III

Other name :

Samarium(III) triflate

Chemical Properties

Formula : Sm(SO3CF3)3
Formula weight : 597.56
Sensitivity : Hygroscopic. Ambient temperatures.
Solubility : Insoluble in water.

Literature References

Effective catalyst for the Baylis-Hillman reaction, using 1,4-Diazabicyclo[2.2.2]octane, A14003: J. Org. Chem., 63, 7183 (1998). The uses of rare-earth metal triflates in organic synthesis have been reviewed by S. Kobayashi: Synlett, 689 (1994); Chem. Rev., 102, 2227 (2002).

Notes

Hygroscopic. Store in a cool, dry place in a tightly closed containers. Stable under recommended storage conditions. Incompatible with oxidizing agents and moisture.Other References:UN#: UN3261

Grade Specifications

Grade Specifications

Hazard Statements : H315-H319-H335Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements : P261-P305+P351+P338-P302+P352-P321-P405-P501aAvoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF ON SKIN: Wash with plenty of soap and water.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.